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as the monodentate ligands A are substituted by monodentate ligands B or by symmetrical bidentate ligands, denoted C—C. Bidentate ligand C—C can only link between two atoms on adjacent positions, i.e. those positions connected by a line in the structures . X, Y, and . Z.

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The incubation mixtures were separated by a bidentate-C18 column, and then analyzed by on-line ion trap/time-of-flight mass spectrometry. With the assistance of mass defect filtering technique, full-scan accurate mass datasets were processed for the discovery of the related metabolites.

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